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Radical Fluoroalkylation Reactions
(American Chemical Society, 2018-08)
Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic ...
Green sample preparation strategies for organic/inorganic compounds in environmental samples
(Elsevier Science, 2019-10)
A rigorous evaluation of environmental contamination requires constant innovation in analytical approaches to gain early identification and accurate quantification of every substance able to compromise health and well-being. ...
New aspects of the surface chemistry of sulfur on Au(111): Surface structures formed by gold-sulfur complexes
(Elsevier Science, 2019-09)
Sulfur adsorption on gold surfaces has been extensively studied because of the key role of sulfur species in heterogeneous catalysis, and, more recently, due to the interest in the synthesis of anisotropic gold nanoparticles ...
Structural, electronic, and thermochemical preference for multi-PCET reactivity of ruthenium(II)-amine and ruthenium(IV)-amido complexes
(Wiley VCH Verlag, 2021-10-21)
The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/amido complexes with multi- ...
Education and complexity: a possible dialogueEducação e complexidade: um diálogo possível
(Universidade Federal de Santa Maria, 2018)
Organizations, reliability and technologyOrganizações, confiabilidade e tecnologia
(RAE - Revista de Administracao de EmpresasRAE - Revista de Administração de EmpresasRAE-Revista de Administração de Empresas, 2005)
Chromium(0) and Molydenum(0) Complexes with a Pyridyl-Mesoionic Carbene Ligand: Structural, (Spectro)electrochemical, Photochemical, and Theoretical Investigations
(American Chemical Society, 2020-10)
This work reports on the synthesis and in-depth electrochemical and photochemical characterization of two chromium(0) and molydenum(0) metal complexes with bidentate pyridyl-mesoionic carbene (MIC) ligands of the ...
Incipient Organization and Socio-Public Spaces: Three Andean CasesOrganización y espacios sociopúblicos incipientes: tres casos de los Andes
(Pontificia Universidad Católica del Perú, 2006)
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
(Royal Society of Chemistry, 2017-06)
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex ...