info:eu-repo/semantics/article
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
Fecha
2017-06Registro en:
Yerien, Damián Emilio; Barata Vallejo, Sebastian; Camps, B.; Cristófalo, Alejandro Ezequiel; Cano, María Emilia; et al.; Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator; Royal Society of Chemistry; Catalysis Science and Technology; 7; 11; 6-2017; 2274-2282
2044-4761
CONICET Digital
CONICET
Autor
Yerien, Damián Emilio
Barata Vallejo, Sebastian
Camps, B.
Cristófalo, Alejandro Ezequiel
Cano, María Emilia
Uhrig, Maria Laura
Postigo, Jose Alberto
Resumen
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI.