article
Phase transition and magnetocaloric properties of Mn50Ni42−xCoxSn8 (0 ≤ x ≤ 10) melt-spun ribbons
Registro en:
Li, Z., Jiang, Y., Li, Z., Sánchez Valdés, C. F., Sánchez Llamazares, J. L., Yang, B., … Zuo, L. (2018). Phase transition and magnetocaloric properties of Mn50Ni42-x Co x Sn8 (0 ? x ? 10) melt-spun ribbons. IUCrJ, 5(Pt 1), 54–66. doi:10.1107/S2052252517016220
Autor
Li, Zongbin
Jiang, Yiwen
Li, Zhenzhuang
Sánchez Valdés, César Fidel
Sánchez Llamazares, José Luis
Yang, Bo
Zhang, Yudong
Esling, Claude
Zhao, Xiang
Zuo, Liang
Resumen
"The characteristics of magnetostructural coupling play a crucial role in the magnetic field-driven behaviour of magnetofunctional alloys. The availability of magnetostructural coupling over a broad temperature range is of great significance for scientific and technological purposes. This work demonstrates that strong magnetostrucural coupling can be achieved over a wide temperature range (222 to 355?K) in Co-doped high Mn-content Mn50Ni42?xCoxSn8 (0 ? x ? 10) melt-spun ribbons. It is shown that, over a wide composition range with Co content from 3 to 9?at.%, the paramagnetic austenite first transforms into ferromagnetic austenite at T C on cooling, then the ferromagnetic austenite further transforms into a weakly magnetic martensite at T M. Such strong magnetostructural coupling enables the ribbons to exhibit field-induced inverse martensitic transformation behaviour and a large magnetocaloric effect. Under a field change of 5?T, a maximum magnetic entropy change ?S M of 18.6?J?kg?1?K?1 and an effective refrigerant capacity RC eff of up to 178?J?kg?1 can be achieved, which are comparable with or even superior to those of Ni-rich Ni–Mn-based polycrystalline bulk alloys. The combination of high performance and low cost makes Mn–Ni–Co–Sn ribbons of great interest as potential candidates for magnetic refrigeration."