Artículo
Fast reduction of Cr(VI) from aqueous solutions using alumina
Autor
GLORIAS GARCIA, FABIOLA; 482043
ARRIAGA MERCED, JOSE MIGUEL; 411521
ROA MORALES, GABRIELA; 121592
VARELA GUERRERO, VICTOR; 219131
BARRERA DIAZ, CARLOS EDUARDO; 25379
Bilyeu, Bryan;#0000-0002-3937-1269
GLORIAS GARCIA, FABIOLA
ARRIAGA MERCED, JOSE MIGUEL
ROA MORALES, GABRIELA
VARELA GUERRERO, VICTOR
BARRERA DIAZ, CARLOS EDUARDO
Bilyeu, Bryan
Institución
Resumen
artículo ya publicado Hexavalent chromium is challenging to remove from industrial wastewater due the solubility and anionic nature of the chromates. Cr(VI) is typically removed by reduction to Cr(III), then precipitation or adsorption, which requires multiple steps and bulk reagents and generates sludge. In this project, we have evaluated a sintered alumina disk as a single step sorbent for Cr(VI). The disk was porous enough that 20 mL samples passed through in about 3 s using light suction. A single pass through the disk only reduced the [Cr(VI)] by 10–20%, but by passing the solution through the disk five times up to 80% was removed in samples up to 130 mg/L and up to around 50% for much higher concentrations. The five passes through the filter disk took less than a minute. On each pass through the disk the characteristic chromate UV–vis absorbance decreased, the Cr(VI) concentration (by the diphenylcarbazide method) decreased, and the pH rose slightly. The XRD pattern showed no change in the crystal structure of the alumina, but the SEM/EDS identified chromium on the surface. In addition to confirming chromium on the surface of the alumina, the XPS spectra showed a change in the binding energy of the aluminum, which is consistent with complexation. The system was fast and effective (in series), so should be applicable to industrial wastewater treatment. UAEMex, CONACyT