Artículo de revista
Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn 4(HPO 4) 4(phen) 4](H 3PO 4) 2(H 2O) 4
Fecha
2005Registro en:
Crystal Growth and Design, Volumen 5, Issue 5, 2018, Pages 1695-1697
15287483
10.1021/cg0502690
Autor
Venegas Yazigi, Diego
Cubillos, M.
Le Fur, E.
Pivan, J. Y.
Garland, María Teresa
Baggio, Ricardo
Spodine Spiridonova, Evgenia
Institución
Resumen
A novel molecular tetrameric zinc cluster with phosphate bridges has been synthesized by a hydrothermal method and characterized by X-ray diffraction. The structure is stabilized by neutral H 3PO 4 and water molecules. Both phosphorus and water oxygen atoms play a central role as connecting agents in this planar, weblike array. Protruding phenanthroline ligands bonded to the zinc atoms are present both above and below the plane, constituting the main interaction between neighboring planes, through π-π stacking. The distance between ring centroids varies between 3.489 and 4.109 Å. © 2005 American Chemical Society.