Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn 4(HPO 4) 4(phen) 4](H 3PO 4) 2(H 2O) 4

dc.creatorVenegas Yazigi, Diego
dc.creatorCubillos, M.
dc.creatorLe Fur, E.
dc.creatorPivan, J. Y.
dc.creatorGarland, María Teresa
dc.creatorBaggio, Ricardo
dc.creatorSpodine Spiridonova, Evgenia
dc.date.accessioned2018-12-20T15:20:45Z
dc.date.available2018-12-20T15:20:45Z
dc.date.created2018-12-20T15:20:45Z
dc.date.issued2005
dc.identifierCrystal Growth and Design, Volumen 5, Issue 5, 2018, Pages 1695-1697
dc.identifier15287483
dc.identifier10.1021/cg0502690
dc.identifierhttps://repositorio.uchile.cl/handle/2250/158896
dc.description.abstractA novel molecular tetrameric zinc cluster with phosphate bridges has been synthesized by a hydrothermal method and characterized by X-ray diffraction. The structure is stabilized by neutral H 3PO 4 and water molecules. Both phosphorus and water oxygen atoms play a central role as connecting agents in this planar, weblike array. Protruding phenanthroline ligands bonded to the zinc atoms are present both above and below the plane, constituting the main interaction between neighboring planes, through π-π stacking. The distance between ring centroids varies between 3.489 and 4.109 Å. © 2005 American Chemical Society.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceCrystal Growth and Design
dc.subjectChemistry (all)
dc.subjectMaterials Science (all)
dc.subjectCondensed Matter Physics
dc.titleOrgano-inorganic tetrameric zinc cluster with phosphate bridges. [Zn 4(HPO 4) 4(phen) 4](H 3PO 4) 2(H 2O) 4
dc.typeArtículo de revista


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