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Rhodium(III) and ruthenium(II) complexes with the chiral phosphine-alcohol PH2PCH2CHMeCH2OH. Synthesis and characterisation
(SOC CHILENA QUIMICA, 2002)
Reaction of the dinuclear complex [{(eta(5)-C5Me5)RhCl}(2)(mu-Cl)(2)] with the chiral phosphine (R)-Ph2PCH2CHMeCH2OH leads to the complex [{(eta(5)-C5Me5)RhCl2(eta(1)-Ph2PCH2CHMeCH2OH-P)}](1). This reaction, in the presence ...