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Interpretation of the experimental data on the reduction reaction of NO by CO on rhodium by Monte Carlo simulations and by solving the kinetic equations of the reaction mechanism
(AMER CHEMICAL SOC, 2006-04-20)
Some mechanisms of the reduction reaction of NO by CO on rhodium are analyzed and discussed, solving the kinetics equations and using Monte Carlo simulations, in terms of its ability to interpret the recent experiments of ...
Mechanism and kinetics parameters of the reduction reaction of NO by CO on Pd/Al2O3 catalyst
(AMER CHEMICAL SOCIETY, 2007-05)
By means of a mechanism similar to that used by Peden and Permana for the reduction reaction of NO by
CO on Rh and the analytical solution of its kinetics equations, a set of kinetics parameters that interpret some
experimental ...
Kinetics and mechanism of the reaction of a nitroxide radical (tempol) with a phenolic antioxidant
(2003)
In the absence of redox-active transition metal ions, the removal of Tempol by Trolox occurs by a simple bimolecular reaction that, most probably, involves a hydrogen transfer from phenol to nitroxide. The specific rate ...
A kinetic study of the 1,3-dipolar cycloaddition reaction between N-p-methoxybenzyliden-α-phenylglycine methyl ester and nitrosobenzene
(1997)
The kinetics of the reaction between N-p-methoxybenzyliden-cc-phenylglycine methyl ester and nitrosobenzene, using benzene as the solvent and both acetic and chloroacetic acid as catalysts, was studied by means of UV-VIS ...
Time Decay of the Activity of the Reduction Reaction of NO by CO on a Pd/Al2O3 Catalyst
(SPRINGER, 2008-11)
An experimental study is made of the time decay of activity of the CO-NO reaction on a Pd/Al2O3 looking at the effect on reaction order and apparent activation energy. The optimum kinetics parameters fitting the steady ...
Monte Carlo study of the influence of the structural heterogeneity of the surface in the CO-NO reaction on Pd and its relation with experimental data
(ELSEVIER, 2008-09-22)
The reduction reaction of NO by CO over Pd is studied by means of a Monte Carlo simulation. A reaction mechanism similar to that established previously in the literature for Rh and a set of recently published kinetics ...
The mechanism of Menshutkin reaction in gas and solvent phases from the perspective of reaction electronic flux
(Springer Verlag, 2014)
© 2014, Springer-Verlag Berlin Heidelberg.The mechanism of Menshutkin reaction, NH3 + CH3Cl = [CH3–NH3]+ + Cl-, has been thoroughly studied in both gas and solvent (H2O and cyclohexane) phase. It has been found that solvents ...
Mechanistic insights into the ANRORC-like rearrangement between methylhydrazine and 1,2,4-oxadiazole derivatives
(Royal Soc Chemistry, 2015)
We herein present the first in-depth theoretical study devoted to elucidate the mechanism of the
reaction between 1,2,4-oxadiazole derivatives and methylhydrazine. For this purpose, the
reaction between methylhydrazine ...
A kinetic study of the reaction between 2-p-methoxyphenyl-4-phenyl-2-oxazolin-5-one and 2,2,6,6-tetramethyl-1-piperidinyl-N-oxide
(SOCIEDAD CHILENA DE QUIMICA, 2000-03)
The reaction between 2-p-methoxyphenyl-4-phenyl-2-oxazolin-5-one and 2,2,6,6-tetramethyl-1-piperidinyl-N-oxide (TEMPO) in benzene as the solvent generates quantitatively 4,4'-bis-[2-p-methoxyphenyl-4-phenyl-2-oxazolin-5-one]. ...
Rate constants determined by nuclear magnetic resonance
(Academic Press, 2001)
Fast kinetic methods are used to measure reactions that take place in less time than required to mix the reagents manually and to measure the reaction by usual methods, like UV-visible spectrophotometry and fluorescence. ...