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Transition-metal-free one-pot synthesis of alkynyl selenides from terminal alkynes under aerobic and sustainable conditions
(Beilstein-Institut, 2017-05)
Alkynyl selenides were synthesized by a straightforward one-pot and three-step methodology, without the need of diselenides as starting reagents, under an oxygen atmosphere and using PEG 200 as the solvent. This procedure ...
Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles
(Georg Thieme Verlag Kg, 2018-11)
The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H 2 balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles ...
Unsupported Copper Nanoparticles in the 1,3-Dipolar Cycloaddition of Terminal Alkynes and Azides
(Wiley VCH Verlag, 2010-04)
Readily prepared copper nanoparticles were found to catalyse the 1,3-dipolar cycloaddition of azides and alkynes up to rates comparable to those of microwave chemistry. Both the preparation of the nanoparticles and the ...
Copper nanoparticles in click chemistry: an alternative catalytic system for the cycloaddition of terminal alkynes and azides
(Pergamon-Elsevier Science Ltd, 2009-03)
Readily prepared copper nanoparticles have been found to effectively catalyse the 1,3-dipolar cycloaddition of a variety of azides and alkynes furnishing the corresponding 1,2,3-triazoles in excellent yields. Both the ...
Base-Free Direct Synthesis of Alkynylphosphonates from Alkynes and H-Phosphonates Catalyzed by Cu2O
(American Chemical Society, 2016-03-04)
A simple and mild methodology for the direct synthesis of alkynylphosphonates is presented. The reaction of a variety of terminal alkynes with dialkyl phosphites in the presence Cu2O (14 mol %) led to the formation of the ...
Cross-Dehydrogenative Coupling of Tertiary Amines and Terminal Alkynes Catalyzed by Copper Nanoparticles on Zeolite
(Wiley, 2015-10)
A wide range of catalysts based on supported copper nanoparticles have been prepared and tested in the cross-dehydrogenative coupling of tertiary amines and terminal alkynes. Copper nanoparticles on zeolite Y were found ...
Orthopalladacycles derived from alpha-diphenylhydrazonoketene dithioacetals and their reactivity with terminal alkynes
(ELSEVIER, 2005-01-17)
In this paper, we present the synthesis and characterization of new orthopalladated complexes derived from alpha-diphenylhydrazonoketene dithioacetals. From their reaction with terminal alkynes, the intermediates of the ...
Zinc triflate as Lewis acid in nucleophilic addition to cyclic N-acyliminium ions
(Georg Thieme Verlag KgStuttgartAlemanha, 2005)