A new class of chiral beta-amino disulfides was synthesized from readily available and inexpensive starting materials by a straightforward method and their abilities as ligands were examined in the enantioselective addition ...

Reaction of the chiral compound (S)-(+)-BrCH2CHMeCH2OH with Ph2PK in the presence of lithium diisopropylamide (LDA) and BH3/THF yields the monophosphine (S)-Ph2P(BH3)CH2CHMeCH2OH(1). The reaction of 1 with ClOSO2Me/Et2N ...

Reaction of the dinuclear complex [{(eta(5)-C5Me5)RhCl}(2)(mu-Cl)(2)] with the chiral phosphine (R)-Ph2PCH2CHMeCH2OH leads to the complex [{(eta(5)-C5Me5)RhCl2(eta(1)-Ph2PCH2CHMeCH2OH-P)}](1). This reaction, in the presence ...

The synthesis of new chiral amino alcohols by Heck arylation of an enecarbamate is described. These compounds were used as chiral ligands for the catalytic asymmetric arylation of aldehydes and can be easily recovered. ...

A synthetic strategy has been developed for the preparation of immobilized 1,2-aminoalcohols starting from easily available and renewable chiral building blocks. They were tested as chiral ligands for the asymmetric ...

We have developed a simple procedure for the preparation of chiral 1,3-aminoalcohols using the biomass derivative levoglucosenone, as the chiral starting material. 1,3-aminoalcohols, bearing primary and tertiary amino ...