Artículos de revistas
Chiral Triphenylprolinol Ligands for the Efficient Catalytic Asymmetric Arylation of Aldehydes
Fecha
2010Registro en:
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, n.19, p.3696-3703, 2010
1434-193X
10.1002/ejoc.201000336
Autor
MORO, Angelica Venturini
TIEKINK, Edward R. T.
ZUKERMAN-SCHPECTOR, Julio
LUEDTKE, Diogo S.
CORREIA, Carlos Roque D.
Institución
Resumen
The synthesis of new chiral amino alcohols by Heck arylation of an enecarbamate is described. These compounds were used as chiral ligands for the catalytic asymmetric arylation of aldehydes and can be easily recovered. Chiral, nonracemic diarylmethanols were obtained in high yields and enantioselectivities.