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Formic Acid Electrooxidation on Platinum, Resolution of the Kinetic Mechanism in Steady State and Evaluation of the Kinetic Constants
(Wiley Blackwell Publishing, Inc, 2018-09)
A kinetic mechanism recently proposed for the formic acid oxidation (FAO) on platinum in acid solutions was analytically solved in order to verify its capability to correlate experimental measurements in steady state ...
Braiding kinetics and spectroscopy in photo-catalysis: the spectro-kinetic approach
(Royal Society of Chemistry, 2019-01)
The combination of kinetic and spectroscopic tools has become a key scientific methodology for the understanding of catalytic behavior but its application in photocatalysis has inherent difficulties due to the nature of ...
Kinetic study of the esterification of free fatty acid and ethanol in the presence of triglycerides using solid resins as catalyst
(Oxford University Press, 2012-12-30)
Biodiesel production is gaining more and more relevance due to its environmental advantages and because of the world situation of petroleum: decreases of reserves, augmentation of prices etc. Biodiesel is produced by ...
Kinetic oscillations in the NO+CO reaction on the Pt(100) surface: an alternative reaction mechanism
(American Institute of Physics, 2005-04)
Kinetic oscillations in the catalytic reduction of NO by CO on a reconstructing Pt(100) surface are simulated by using a dynamic Monte Carlo method. The simulation is based on the HS model and takes into account an alternative ...
Optimized benzaldehyde production over a new Co-ZSM-11 catalyst: Reaction parameters effects and kinetics
(Elsevier Science, 2014-02)
An efficient Co-ZSM-11 catalyst has been synthesized for benzaldehyde production by the selective styrene oxidation. Reaction parameters such as catalyst mass, reaction temperature, molar ratio styrene/hydrogen peroxide ...
Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
(Electrochemical Society, 2009-01)
The present work deals with a kinetic study of the hydrogen electrode reaction (HER) on a platinum electrode modified by bismuth adatoms in both cathodic and anodic range of overpotentials. Kinetic expressions previously ...
The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction
(Pergamon-Elsevier Science Ltd, 2007-12)
An alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the ...
Analysis of the hydrogen electrode reaction mechanism in thin-layer cells. 3. Study of hydrogen electro-oxidation by scanning electrochemical microscopy
(Elsevier Science Sa, 2017-01)
Scanning electrochemical microscopy (SECM) in the feedback mode was used to analyze the complete mechanism of the hydrogen oxidation reaction (hor). A general SECM equation was proposed to carry out the kinetic analysis ...
A kinetic and mechanistic study on the thermal decomposition reactions of cis- and trans- fused 1,2,4-trioxanes
(Asociación de Químicos e Ingenieros, 2003-09)
The kinetics of the thermal decomposition reactions of artemisinine (1), a cis-fused 1,2,4-trioxane, and trans-3,3dimethyl-1,2,4-trioxane (6) in solutions of benzene, toluene, and methanol in sealed tubes were compared at ...