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Application of Amine-based Ru Compounds in the Olefin Metathesis of Methyl Eugenol: A Comparison with Grubbs Catalysts
(Bentham Science Publ Ltd, 2020-01-01)
Methyl eugenol olefin metathesis was conducted with non-carbene Ru-complexes ([RuCl2(PPh3)(2)amine]) in the absence and presence of SnCl2 or CuCl2 as additives and their catalytic activities were compared with that of a ...
Solid-supported cross-metathesis and a formal alkane metathesis for the generation of biologically relevant molecules
(American Chemical Society, 2015-02)
Solid-phase synthetic strategies towards the generation of libraries of biologically relevant molecules were developed using olefin cross-metathesis as a key step. It is remarkably the formal alkane metathesis based on a ...
Reactivity of tungsten-aryloxides with hydrosilane cocatalysts in olefin metathesis
(Soc Brasileira Quimica, 2002-01-01)
The reactivity of the [WCl4(OAr)(2)] (OAr = O-2,6-C3H3Cl2, O-2,6-C6H3F2 and O-C6H3Me2) systems, plus the silicon compounds Ph2SiH2 and polymethylhydrosiloxane (PMHS), were studied in metathesis reactions. The olefins used ...
Germanium and silicon compounds as promoters for Re2O7/SiO2-Al2O3 metathesis catalysts
(Elsevier Science BvAmsterdamHolanda, 2002)
Reactivity of Tungsten-aryloxides with Hydrosilane Cocatalysts in Olefin Metathesis
(Sociedade Brasileira de Química, 2014)
Molecular diversity by olefin cross-metathesis on solid support. Generation of libraries of biologically promising β-lactam derivatives
(Molecular Diversity Preservation International, 2018-05)
The application of the reagent-based diversification strategy for generation of libraries of biologically promising β-lactam derivatives is described. Key features are the versatility of the linker used and the cross-metathesis ...
Unravelling the olefin cross metathesis on solid support. Factors affecting the reaction outcome
(Royal Society of Chemistry, 2010-06)
Olefin cross metathesis on solid support under a variety of conditions is described. A comprehensive analysis considering diverse factors governing the reaction outcome gives a series of patterns for the application of ...
INFLUENCE OF THE STERIC HINDRANCE OF ANCILLARY LIGANDS IN Ru-BASED COMPLEXES APPLIED IN METATHESIS OF CINNAMYL ALCOHOL AND CINNAMYL ACETATE
(Soc Brasileira Quimica, 2020-01-01)
Cinnamyl alcohol (AC) and cinnamyl acetate (ACM) were used as substrates in olefin metathesis reactions catalyzed by RuCl2(PCy3)(2)(=CHPh), first-generation Grubbs catalyst-G1, and RuCl2(PCy3)(H(2)Mes)(= CHPh), second-generation ...