This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic ...

Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. ...

In this work, we present a room- or solar-light-initiated transition-metal-free radical homolytic aromatic substitution (HAS) reaction of aniline derivatives with perfluoroalkyl moieties employing perfluoroalkyl halides ...

Perfluorobutylation of a series of benzo(hetero)aromatic compounds without formal leaving groups is achieved efficaciously in organic solvent-water mixtures under photostimulation. The methodology is compared with previously ...

Perfluorobutylation of a series of benzo- and dibenzo-(hetero)aromatic compounds without formal leaving groups is achieved efficiently in organic solvent: water mixtures under photostimulation. The methodology is compared ...

Perfluorobutylation of a series of benzo- and dibenzo-(hetero)aromatic compounds without formal leaving groups is achieved efficiently in organic solvent: water mixtures under photostimulation. The methodology is compared ...

Most of the radical reactions can be conducted under mild conditions. In contrast to ionic reactions and many transition-metal mediated processes most of the functional groups are tolerated under radical conditions. Moreover, ...

We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a ...

Conceptually different approach toward biaryl syntheses by photoinduced direct CH arylation of benzene and thiophene in the presence of t-BuOK is reported. The reaction proceeds through photo- and base-promoted homolytic ...