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Homofugality: A new reactivity index describing the leaving group ability in homolytic substitution reactions
Fecha
2006-06-24Registro en:
CHEMICAL PHYSICS LETTERS Volume: 424 Issue: 4-6 Pages: 437-442 Published: JUN 24 2006
0009-2614
Autor
Guerra, Doris
Castillo, Raquel
Andrés, Juan
Fuentealba Rosas, Patricio
Aizman, Arie
Contreras Ramos, Renato
Institución
Resumen
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a series of S(H)2 processes involving organometallic systems.