info:eu-repo/semantics/article
Radical amination with trimethylstannylated benzophenone imine
Fecha
2010-04Registro en:
Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido; Radical amination with trimethylstannylated benzophenone imine; American Chemical Society; Organic Letters; 12; 9; 4-2010; 2072-2075
1523-7060
Autor
Lamas, Marie-Céline
Vaillard, Santiago Eduardo
Wibbeling, Birgit
Studer, Armido
Resumen
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.