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Solution versus Fluorous versus Solid-Phase Synthesis of 2,5-Disubstituted 1,3-Azoles. Preliminary Antibacterial Activity Studies
(American Chemical Society, 2009-11)
A small library of compounds with an oxa(thia)zole scaffold and structural diversity in both positions 2 and 5 has been synthesized. Double acylation of a protected glycine affords intermediate α-amido-β-ketoesters, which ...
Reactivity of fluorinated organic radicals in aqueous media
(Wiley VCH Verlag, 2012-04)
Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl ...
Improved Regioselectivity in Pyrazole Formation through the Use of Fluorinated Alcohols as Solvents: Synthesis and Biological Activity of Fluorinated Tebufenpyrad Analogs
(American Chemical Society, 2008-12)
The preparation of N-methylpyrazoles is usually accomplished through reaction of a suitable 1,3-diketone with methylhydrazine in ethanol as the solvent. This strategy, however, leads to the formation of regioisomeric ...
Synthesis of new fluorous modular chiral ligand derivatives from amino alcohols and application in enantioselective carbon-carbon bond-forming alkylation reactions
(PERGAMON-ELSEVIER SCIENCE LTD, 2010)
N-Trifluoracyl beta-chalcogeno amides and N-perfluoracyl beta-thio amide ligands were prepared by a simple and efficient reaction sequence. These new ligands were evaluated in palladium-catalyzed alkylation of rac-(E)-1, ...
Fluorous molecules for dye-sensitized solar cells: Synthesis and properties of di-branched, di-anchoring organic sensitizers containing fluorene subunits
(Royal Society of Chemistry, 2017-06)
Four organic sensitizers having a di-branched molecular structure D-(π-A)2 (D = para-substituted arylamine, π = 9,9-dibutylfluorene, A = cyanoacrylic acid) were synthesized, characterized, and applied in the development ...
(Me3Si)3SiH-mediated intermolecular radical perfluoroalkylation reactions of olefins in water
(American Chemical Society, 2010-09)
Figure presented. Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved ...
(Me3Si)3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different ...
Mineral chemistry of micas from the Serra Branca granitic massif – Goiás State - Brazil: hydrothermal alteration processes as modifiers of the crystalochemical reequilibriumQuímica mineral de micas do maciço granítico Serra Branca, Goiás: processos de alteração hidrotermal como modificadores do reequilíbrio cristaloquímico
(Sociedade Brasileira de Geologia, 2016)