Artículos de revistas
Ionic Liquids And The Heck Coupling Reaction: An Update
Registro en:
Current Organic Chemistry. , v. 17, n. 3, p. 238 - 256, 2013.
13852728
10.2174/1385272811317030006
2-s2.0-84879231977
Autor
Prediger P.
Genissona Y.
Correiab C.R.D.
Institución
Resumen
In this review update we provide a critical analysis of recent results concerning the use of ionic liquids (ILs) as viable, effective, and environmental friendly media for the Heck reactions (HR). The examples selected illustrate the multifaceted action of ILs as nanoparticles stabilizers, promoters of ligand-assisted HR, promoters of phosphine-free HR, solvent for the Heck-Matsuda reactions employing arenediazonium salts, in the dehydrative Heck olefination, and as charged-tagged pre-catalysts. These selected reports aim at demonstrating the scope and the impact of Ils on new discoveries, as well as to illustrate the new opportunities and challenges they offer for those interested in catalysis and organic synthesis in general. © 2013 Bentham Science Publishers. 17 3 238 256 Hallett, J.P., Welton, T., Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 (2011) Chem. Rev, 111, pp. 3508-3576 Sun, P., Armstrong, D.W., Ionic liquids in analytical chemistry (2010) Anal. 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