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Mesogenic Coordination Polymers Based on Ru2(II,II)-Paddle-Wheel Units Exhibit High Electrical Conductivity
(Wiley VCH Verlag, 2021-12)
We report the synthesis, characterization and properties of a series of coordination polymers (CP) in which paddle-wheel diruthenium (II,II) tetracarboxylate units are linked by tetrazine as axial ligand, a combination ...
Enhancing automated reaction discovery with boxed molecular dynamics in energy space
(WILEY-VCH Verlag GmbH & Co. KGaA, 2019-09)
The rare event acceleration method BXDE is interfaced inthe present work with the automated reaction discovery methodAutoMeKin. To test the efficiency of the combined AutoMeKin-BXDEprocedure, the ozonolysis of -pinene is ...
The sensation seeking scale (SSS-V) and its use in Latin American adolescents: Alcohol consumption pattern as an external criterion for its validation
(PsychOpen, 2017-12)
Sensation Seeking is a trait defined by the seeking of varied, novel, complex, and intense situations and experiences, and the willingness to take physical, social, and financial risks for the sake of such experience. The ...
From organizational justice perceptions to turnover intentions: The mediating effects of burnout and job satisfaction
(PsychOpen, 2018-08)
Turnover intentions (TI) stand as an insidious problem that impacts on the functioning of organizations and the well-being of their members. Currently, there is a growing interest in identifying the explanatory mechanisms ...
Two different thiosemicarbazone tauto-conformers coordinate to Palladium (II): Stability and biological studies of the final complexes
(Wiley VCH Verlag, 2021-03-19)
Thiosemicarbazone moiety is a valuable scaffold for the synthesis of metallic complexes with anticancer purposes, when bearing N-heterocyclic the final compounds possess diverse biological activities. Using thiazole as ...
Uncovering the mechanism leading to the synthesis of symmetric and asymmetric Tröger's bases
(Wiley VCH Verlag, 2019-11)
Tröger´s bases have been attracting great interest due to their potential applications in nanoelectronics, supramolecular chemistry, molecular recognition, biological activity and auxiliaries for asymmetric synthesis. ...
Photostable, Amino Reactive and Water-Soluble Fluorescent Labels Based on Sulfonated Rhodamine with a Rigidized Xanthene Fragment
(Wiley VCH Verlag, 2008-02)
Highly water soluble fluorescentdyes were synthesized and transformedinto new amino reactive fluorescentlabels for biological microscopy.To this end,rhodamine 8 (preparedfrom 7-hydroxy-1,2,3,4-tetrahydroquinoline(7) and ...
Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex
(Wiley VCH Verlag, 2010-12)
We report the properties of a trinuclear cyanido-bridged complex, trans-(dmap)4RuII(Âμ-NC)OsIII(CN) 524- [14-; dmap = 4-(dimethylamino)pyridine], whose structure and electronic and vibrational spectra present strong evidence ...
Mesostructured electroactive thin films through layer-by-layer assembly of redox surfactants and polyelectrolytes
(Wiley VCH Verlag, 2020-08)
Electroactive thin films are an important element in the devices devoted to energy conversion, actuators, and molecular electronics, among others. Their build-up by the layer-by-layer technique is an attractive choice since ...
Light-harvesting antenna and proton-activated photodynamic effect of a novel BODIPY-fullerene C60 dyad as potential antimicrobial agent
(Wiley VCH Verlag, 2019-03)
A covalently linked BODIPY−fullerene C 60 dyad (BDP−C 60 ) was synthesized as a two-segment structure, which consists of a visible light-harvesting antenna attached to an energy or electron acceptor moiety. This structure ...