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Quantum entanglement and the dissociation process of diatomic molecules
(IOP Publishing, 2011-09)
In this work, we investigate quantum entanglement-related aspects of the dissociation process of some selected, representative homo- and heteronuclear diatomic molecules. This study is based upon high-quality ab initio ...
New insights into the reaction paths of hydroxyl radicals with purine moieties in DNA and double-stranded oligodeoxynucleotides
(Molecular Diversity Preservation International, 2019-10)
The reaction of hydroxyl radical (HO•) with DNA produces many primary reactive species and many lesions as final products. In this study, we have examined the optical spectra of intermediate species derived from the reaction ...
Atmospheric oxidation of α,β-unsaturated ketones: Kinetics and mechanism of the OH radical reaction
(Copernicus Publications, 2021-09)
The OH-radical-initiated oxidation of 3-methyl-3-penten-2-one and 4-methyl-3-penten-2-one was investigated in two atmospheric simulation chambers at 298±3 K and 990±15 mbar using long-path FTIR spectroscopy. The rate ...
Glow Discharge in a High-Velocity Air Flow: The Role of the Associative Ionization Reactions Involving Excited Atoms
(Molecular Diversity Preservation International, 2019-08)
A kinetic scheme for non-equilibrium regimes of atmospheric pressure air discharges is developed. A distinctive feature of this model is that it includes associative ionization with the participation of N(2D, 2P) atoms. ...
Glow discharge in a high-velocity air flow: The role of the associative ionization reactions involving excited atoms
(Multidisciplinary Digital Publishing Institute, 2019-08)
A kinetic scheme for non-equilibrium regimes of atmospheric pressure air discharges is developed. A distinctive feature of this model is that it includes associative ionization with the participation of N(2D, 2P) atoms. ...
Photooxidation of 9-anthraldehyde catalyzed by gold nanoparticles: Solution and single nanoparticle studies using fluorescence lifetime imaging
(American Chemical Society, 2012-11)
The photooxidation of 9-anthraldehyde can be catalyzed by colloidal Au nanoparticles (AuNP) or diamond-supported Au nanoparticles (AuNCD) by using LED excitation at 530 nm. Visible irradiation of the plasmon band of AuNP ...
Catalytic behavior of niobia species on oxidation reactions: Insights from experimental and theoretical models
(Springer, 2008-09)
This paper describes the preparation and use of a new class of material based on synthetic Niobia as catalysts in oxidizing reactions of organic compounds in aqueous medium. The reaction chemicals were carried out in ...
Light on the horizon: Current research and future perspectives in flow photochemistry
(American Chemical Society, 2018-09)
Synthetic organic photochemistry is a powerful tool for creating both natural products and molecules with high structural complexity in a simple way and under mild conditions. However, because of the challenges in scaling-up, ...
Nitro-fatty acids: electrophilic signaling molecules in plant physiology
(Springer, 2021-11)
Main conclusion: Nitro fatty acids (NO2-FA)have relevant physiological roles as signaling molecules in biotic and abiotic stress, growth, and development, but the mechanism of action remains controversial. The two main ...