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Keto-ether and glycol-ethers in the troposphere: reactivity toward OH radicals and Cl atoms, global lifetimes, and atmospheric implications
(Springer Heidelberg, 2017-11)
Rate coefficients for the gas-phase reactions of OH radicals and Cl atoms with 1-methoxy-2-propanone (1-M-2-PONE), 1-methoxy-2-propanol (1-M-2-POL), and 1-methoxy-2-butanol (1-M-2-BOL) were determined at room temperature ...
Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
(Royal Society of Chemistry, 2020-03)
Designing molecular platforms for controlling proton and electron movement in artificial photosynthetic systems is crucial to efficient catalysis and solar energy conversion. The transfer of both protons and electrons ...
Kinetics, product distribution and atmospheric implications of the gas-phase oxidation of allyl sulfides by OH radicals
(Pergamon-Elsevier Science Ltd, 2022-02)
Relative rate coefficients of the OH radical -initiated oxidation of allyl methyl sulfide (AMS, H2C[dbnd]CHCH2SCH3) and allyl ethyl sulfide (AES, H2C[dbnd]CHCH2SCH2CH3) have been measured at atmospheric pressure of synthetic ...
The binuclear dual emitter [Br(CO)3Re(P⋯N)(N⋯P)Re(CO)3Br] (P⋯N): 3-chloro-6-(4-diphenylphosphinyl)butoxypyridazine, a new bridging P,N-bidentate ligand resulting from the ring opening of tetrahydrofuran
(Royal Society of Chemistry, 2017-01)
Lithium diphenylphosphide unexpectedly provokes the ring-opening of tetrahydrofuran (THF) and by reaction with 3,6-dichloropyridazine leads to the formation of the ligand 3-chloro-6-(4-diphenylphosphinyl)butoxypyridazine ...
Characterisation of glycoconjugate sugar residues in the vomeronasal organ of the armadillo Chaetophractus villosus (Mammalia, xenarthra)
(Cambridge University Press, 2000-04)
Conventional carbohydrate histochemistry and the binding patterns of 21 lectins were analysed to characterise the glycoconjugate content in the components of the vomeronasal organ of the armadillo Chaetophractus villosus. ...
AII-frans-[CIRuII(py)4(NC)RuII(py) 4(CN)RuII(py)4(N0)](PF6) 4: a redox-active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motif
(American Chemical Society, 2009-01)
The new linear homotrinuclear compound frans-[CIRuII(py) 4(NC)RuII(py)4(CN)RuII(py) 4(NO)](PF6)4 was prepared by reaction between the nitro complex trans-[(NC)RuII(py)4(CN)Ru II(py)4(NO2)]+ and the solvento complex obtained ...
Thermodynamic parameters of adsorption of 1,10-phenanthroline and 2,2′-bipyridyl on hematite, kaolinite and montmorillonites
(Elsevier Science, 2007-07)
The thermodynamic equilibrium constant (K), free energy (ΔG), enthalpy (ΔH), entropy (ΔS), isosteric heat (qst) of adsorption, and the constant (kL) of the Langmuir adsorption equation using the adsorption isotherms (pH ...
Rate coefficients at 298 K and 1 atm for the tropospheric degradationof a series of C6,C7and C8biogenic unsaturated alcohols initiated by Clatoms
(Pergamon-Elsevier Science Ltd., 2014-05)
Rate coefficients for the gas-phase reactions of Cl atoms with a series of unsaturated biogenic alcohols at 298 ± 3 K and 1 atm have been measured by the relative technique in an environmental chamber with in situ FTIR ...
Scattering of Atomic Hydrogen Off a H-Covered W(110) Surface: Hot-Atom versus Eley-Rideal Abstraction Dynamics
(American Chemical Society, 2015)
Kinetic investigation of the OH radical and Cl atom initiated degradation of unsaturated ketones at atmospheric pressure and 298 K
(American Chemical Society, 2012)