Nickel alpha-Keto-beta-Diimine Initiators for Olefin Polymerization

dc.creatorAzoulay, Jason D.
dc.creatorRojas, Rene S.
dc.creatorSerrano, Abigail V.
dc.creatorOhtaki, Hisashi
dc.creatorGalland, Griselda B.
dc.creatorWu, Guang
dc.creatorBazan, Guillermo C.
dc.date.accessioned2024-01-10T12:06:55Z
dc.date.accessioned2024-05-02T18:22:15Z
dc.date.available2024-01-10T12:06:55Z
dc.date.available2024-05-02T18:22:15Z
dc.date.created2024-01-10T12:06:55Z
dc.date.issued2009
dc.identifier10.1002/anie.200804661
dc.identifier1521-3773
dc.identifier1433-7851
dc.identifierMEDLINE:19065683
dc.identifierhttps://doi.org/10.1002/anie.200804661
dc.identifierhttps://repositorio.uc.cl/handle/11534/76223
dc.identifierWOS:000263082300010
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9270222
dc.description.abstract(Figure Presented) A new ligand-metal combination (see picture, Ni green, Br brown, N blue, O red, C gray) was designed to be cationic and to benefit from removal of electron density by the action of a Lewis acid on the ligand framework. In the presence of various activators, the resulting catalytic site is highly active for ethylene polymerization and capable of polymerizing α-olefins to high molecular weights. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
dc.languageen
dc.publisherWILEY-V C H VERLAG GMBH
dc.rightsregistro bibliográfico
dc.subjecthomogeneous catalysis
dc.subjectnickel
dc.subjectpolymerization
dc.subjectsubstituent effects
dc.subjectTRANSITION-METAL-CATALYSTS
dc.subjectLIVING POLYMERIZATION
dc.subjectNI(II) CATALYST
dc.subjectVINYL MONOMERS
dc.subjectETHYLENE
dc.subjectCOPOLYMERIZATION
dc.subjectCOMPLEXES
dc.subjectMETHYLALUMINOXANE
dc.subjectMICROSTRUCTURE
dc.subjectREACTIVITY
dc.titleNickel alpha-Keto-beta-Diimine Initiators for Olefin Polymerization
dc.typeartículo


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