Synthesis and structure of some heterobimetallic complexes having a polyalkyl-s-indacenyl spacer

dc.creatorMorales Verdejo, Cesar
dc.creatorMartinez, Ivan
dc.creatorMac Leod Carey, Desmond
dc.creatorChavez, Ivonne
dc.creatorManuel Manriquez, Juan
dc.creatorMatioszek, Dimitri
dc.creatorSaffon, Nathalie
dc.creatorCastel, Annie
dc.creatorRiviere, Pierre
dc.creatorMolins, Elies
dc.date.accessioned2024-01-10T12:09:06Z
dc.date.accessioned2024-05-02T17:37:54Z
dc.date.available2024-01-10T12:09:06Z
dc.date.available2024-05-02T17:37:54Z
dc.date.created2024-01-10T12:09:06Z
dc.date.issued2013
dc.identifier10.1016/j.ica.2012.09.040
dc.identifier1873-3255
dc.identifier0020-1693
dc.identifierhttps://doi.org/10.1016/j.ica.2012.09.040
dc.identifierhttps://repositorio.uc.cl/handle/11534/76458
dc.identifierWOS:000311492900099
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9268665
dc.description.abstractThree heterobimetallic complexes LmM(s-Ic')M'Ln (M = Fe, Ru or Mn; M' = Ni) having the same Cp* nickel moiety and based on a polyalkyl-s-indacenyl spacer (s-Ic' = 2,6-diethyl-4,8-dimethyl-s-indacenyl) were synthesized by reacting Cp* Ni(acac) with the lithium derivative of the parent monometalated complex. All three compounds were fully characterized and shown to adopt a trans geometry by X-ray crystallography. (C) 2012 Elsevier B. V. All rights reserved.
dc.languageen
dc.publisherELSEVIER SCIENCE SA
dc.rightsacceso restringido
dc.subjectPolyalkyl-s-indacene
dc.subjectNikel indacenyl heterobimetallic complexes: Ni/Fe Ni/Ru, Ni/Mn
dc.subjectX-ray structures
dc.subjectManganese s-indacenyl complex
dc.subjectTRIPLE-DECKER COMPLEXES
dc.subjectAS-INDACENE
dc.subjectELECTRONIC COMMUNICATION
dc.subjectTHERMAL REARRANGEMENT
dc.subjectPENTALENE COMPLEXES
dc.subjectIR(I) COMPLEXES
dc.subjectMIXED-VALENT
dc.subjectREACTIVITY
dc.subjectDERIVATIVES
dc.subjectROUTE
dc.titleSynthesis and structure of some heterobimetallic complexes having a polyalkyl-s-indacenyl spacer
dc.typeartículo


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