Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part II

dc.creatorCatalán, L.E.
dc.creatorMarín, K.C.
dc.creatorAltamirano H.C.
dc.creatorFritis, M.C.
dc.creatorChamy M.C.
dc.date.accessioned2021-06-22T15:20:31Z
dc.date.accessioned2024-05-02T14:58:54Z
dc.date.available2021-06-22T15:20:31Z
dc.date.available2024-05-02T14:58:54Z
dc.date.created2021-06-22T15:20:31Z
dc.date.issued2007-12
dc.identifierMoleculesOpen AccessVolume 12, Issue 12, Pages 2605 - 2620December 2007
dc.identifier1420-3049
dc.identifierhttp://repositorio.unab.cl/xmlui/handle/ria/19148
dc.identifier10.3390/12122605
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9260940
dc.description.abstractA route for the degradation of the side chain of ent-labdane derivatives has been devised, giving the useful synthon 2β,12-dihydroxy-13,14,15,16,17- pentanor-ent-labdane-8-one (8). The use of this compound in the preparation of terpenylquinone derivatives shall be reported elsewhere. In addition we have synthesized the compound 2β,12-diacetoxy-8β,17-epoxy-13,14,15,16- tetranor-ent-labdane (10), which upon catalytic epoxide ring opening in alkaline or acid media gave rise in all cases to the formation of tricyclic compounds. © 2007 by MDPI.
dc.languageen
dc.publisherMDPI
dc.subjectEnt-labdanes
dc.subjectSelective degradations
dc.subjectUnsaturated side chain
dc.titleOxidative degradations of the side chain of unsaturated Ent-labdanes. Part II
dc.typeArtículo


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