Resumo de eventos cient??ficos
Adsorption of bisphenol-A in aqueous solution using silica nanoparticles obtained from sugarcane ash
Autor
ROVANI, SUZIMARA
SANTOS, JONNATAN J.
CORIO, PAOLA
FUNGARO, DENISE A.
AMERICAN CHEMICAL SOCIETY. DIVISION OF CELLULOSE & RENEWABLE MATERIALS. NATIONAL MEETING & EXPOSITION, 255th
Resumen
Scientists around the world have searched minimize problems related to the incorrect disposal of solid
wastes and water contamination. Brazil, for example, is the largest producer of sugarcane in the world,
generates around 3-12 million of tons ash/year or more, and this waste can be transformed into valueadded
material. In this study, we tried to solve two problems at the same time, manufacturing an
adsorbent material and applies it in the remediation of contaminated water with bisphenol-A (BPA), an
endocrine disrupting compounds, which alters plasma sex hormone levels in fishes [1]. The silica
nanoparticles were synthetized through the addition of silicate obtained from sugarcane ash in the
solution of water/butyl alcohol (1:1) with 2.5% wt. of hexadecyltrimethylammonium bromide under
constant stirring. Then, 0.5 mol L-1 H2SO4 solution was added to suspension until pH 4. The nanosilica
formed was washed with distilled water, filtered and dried. The silica nanoparticles and BPA adsorbed on
silica were characterized by different techniques. The maximum BPA adsorption capacity obtained was
80 mg g-1. From TEM images (Fig. 1A-B) of the silica nanoparticles it is seen that all particles has less
than 20 nm. Fig. 1C shows the infrared spectra of samples. The band at 1058 cm-1 is due to the Si???O???Si
asymmetric stretching, the band at 965 cm-1 is due to Si-OH bending vibrational absorption, the bands at
799 and 446 cm-1 are due to the Si???O???Si symmetric stretching. The presence of other bands in the blue
spectra are attributed of BPA adsorbed on silica nanoparticles, at 554 cm-1 is due to aromatic ring
deformation vibration of di-substituted benzenes, at 834 cm-1 is assigned to C-H vibrations out of the
plane and at 1512 cm-1 is due to aromatic C=C stretching vibration [2]. The results of characterization of
the silica nanoparticles manufactured showed that the material presents potential to be employed as
adsorbent for remediation of water contaminated with endocrine disrupting compounds.