Why silver deposition is so fast: Solving the enigma of metal deposition

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorPinto, Leandro M. C.
dc.creatorSpohr, Eckhard
dc.creatorQuaino, Paola
dc.creatorSantos, Elizabeth
dc.creatorSchmickler, Wolfgang
dc.date2014-05-27T11:29:58Z
dc.date2016-10-25T18:51:33Z
dc.date2014-05-27T11:29:58Z
dc.date2016-10-25T18:51:33Z
dc.date2013-07-22
dc.date.accessioned2017-04-06T02:31:26Z
dc.date.available2017-04-06T02:31:26Z
dc.identifierAngewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.
dc.identifier1433-7851
dc.identifier1521-3773
dc.identifierhttp://hdl.handle.net/11449/76014
dc.identifierhttp://acervodigital.unesp.br/handle/11449/76014
dc.identifier10.1002/anie.201301998
dc.identifierWOS:000321896800057
dc.identifier2-s2.0-84880359340
dc.identifierhttp://dx.doi.org/10.1002/anie.201301998
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/896729
dc.descriptionA perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.languageeng
dc.relationAngewandte Chemie - International Edition
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectcorrosion
dc.subjectmetal deposition
dc.subjecttheoretical electrochemistry
dc.subjectElectrochemical reactions
dc.subjectMD simulation
dc.subjectMetal deposition
dc.subjectPerfect matches
dc.subjectSilver deposition
dc.subjectSolvation energy
dc.subjectStrong interaction
dc.subjectCatalysis
dc.subjectChemistry
dc.subjectCorrosion
dc.subjectDeposition
dc.titleWhy silver deposition is so fast: Solving the enigma of metal deposition
dc.typeOtro


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