Artigo
Foaming of EVA/starch blends: Characterization of the structure, physical properties, and biodegradability
Registro en:
Polymer Engineering and Science. Malden: Wiley-blackwell, v. 52, n. 1, p. 62-70, 2012.
0032-3888
10.1002/pen.22046
WOS:000298589600007
1540538724619296
0000-0002-4556-3718
Autor
Rodriguez-Perez, M. A.
Simoes, R. D. [UNESP]
Roman-Lorza, S.
Alvarez-Lainez, M.
Montoya-Mesa, C.
Constantino, C. J. L. [UNESP]
de Saja, J. A.
Resumen
Foams produced from blends of an ethylene-vinyl acetate copolymer (EVA) with high VA (vinyl acetate) content (28%) and corn starch have been successfully fabricated using an improved compression molding technique. A detailed characterization of the structure and physical properties has been carried out. The results showed that the corn starch acts as filler for EVA, showing a good compatibility with the polyolefin. Different types of cellular structure (closed, partially interconnected, and fully interconnected) and cell sizes were obtained depending on the relative density and the amount of starch included in the composition. Besides, the addition of starch allows tailoring the physical properties of the composite foams. An increase in the starch content leads to an increase of the density, compressive strength, hardness, and thermal conductivity and a decrease of the elasticity. Finally, biodegradability tests showed how increases the biodegradation with the amount of starch in the foam, which reaches 60% at 100 days for the foam with 70% of starch. POLYM. ENG. SCI., 2012. (C) 2011 Society of Plastics Engineers Junta of Castile and Leon Spanish Ministry of Science and Innovation FEDER Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Fundacion Carolina, MICINN Univ Valladolid, Fac Sci, Cellular Mat Lab CellMat, Dept Condensed Matter Phys, E-47011 Valladolid, Spain Univ Estadual Paulista, UNESP, Fac Ciencias & Tecnol, BR-19060900 Presidente Prudente, SP, Brazil Eafit Univ, Engn & Prod Design Dept, Engn Mat Res Grp, Medellin, Colombia Univ Estadual Paulista, UNESP, Fac Ciencias & Tecnol, BR-19060900 Presidente Prudente, SP, Brazil Junta of Castile and Leon: GR39 FEDER: MAT 2006 1614-C03-01 FEDER: MAT2009-14001-C02-01 CAPES: 118/06 Fundacion Carolina, MICINN: PHB2005-0057-PC INC 0193