Síntesis y caracterización de derivados cumarín piridínicos y su aplicación en la detección de un ion metálico

dc.contributorGranados Oliveros, Gilma
dc.contributorSíntesis Orgánica Sostenible
dc.creatorSánchez Sierra, Christian Camilo
dc.date.accessioned2023-08-08T21:50:59Z
dc.date.accessioned2023-08-25T13:57:39Z
dc.date.available2023-08-08T21:50:59Z
dc.date.available2023-08-25T13:57:39Z
dc.date.created2023-08-08T21:50:59Z
dc.date.issued2021-11-22
dc.identifierhttps://repositorio.unal.edu.co/handle/unal/84501
dc.identifierUniversidad Nacional de Colombia
dc.identifierRepositorio Institucional Universidad Nacional de Colombia
dc.identifierhttps://repositorio.unal.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/8427035
dc.description.abstractThree new and novel hybrids of coumarin pyridines with a donor π acceptor system were synthesized in a 5-step series, without metal catalysts or special experimental conditions. These compounds were characterized by melting point, IR-TF, 1H NMR, APT and 13C, UV-Vis spectroscopy and fluorescence. Also, mass spectrometry. The photophysical characteristics of the pyridine coumarin derivatives were studied, showing that they are strong emitters of blue light when excited at a λem of 300 nm, reaching quantum yields between 10 and 12%, these were evaluated against various metal ions, showing a high selectivity for Al3+. (Texto tomado de la fuente)
dc.description.abstractTres nuevos y novedosos híbridos de cumarín piridinas con un sistema donor π aceptor fueron sintetizados en una serie de 5 pasos, sin catalizadores metálicos, ni condiciones experimentales especiales. Estos compuestos fueron caracterizados por punto de fusión, IR-TF, RMN 1H, APT y 13C, espectroscopía de UV-Vis y fluorescencia. Además, de espectrometría de masas. Se estudiaron las características fotofísicas de los derivados cumarín piridínicos mostrando ser unos fuertes emisores de luz azul al ser excitados a una λem de 300 nm llegando a tener rendimientos cuánticos entre el 10 y 12 %, estos fueron evaluados frente a diversos iones metálicos, mostrando una alta selectividad por Al3+.
dc.languagespa
dc.publisherBogotá - Ciencias - Maestría en Ciencias - Química
dc.publisherFacultad de Administración
dc.publisherBogotá, Colombia
dc.publisherUniversidad Nacional de Colombia - Sede Bogotá
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dc.rightsReconocimiento 4.0 Internacional
dc.rightshttp://creativecommons.org/licenses/by/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleSíntesis y caracterización de derivados cumarín piridínicos y su aplicación en la detección de un ion metálico
dc.typeTrabajo de grado - Maestría


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