| dc.creator | Woods, Toby James | |
| dc.creator | Ballesteros-Rivas, Maria Fernanda | |
| dc.creator | Gomez-Coca, Silvia | |
| dc.creator | Ruiz, Eliseo | |
| dc.creator | Dunbar, Kim Renee | |
| dc.date | 2018-02-16T19:41:02Z | |
| dc.date | 2018-02-16T19:41:02Z | |
| dc.date | 2016-11-10 | |
| dc.date.accessioned | 2023-07-20T13:03:08Z | |
| dc.date.available | 2023-07-20T13:03:08Z | |
| dc.identifier | 0002-7863 | |
| dc.identifier | http://hdl.handle.net/20.500.11799/68642 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/7716654 | |
| dc.description | A family of isostructural, mononuclear CoII
complexes with distorted trigonal bipyramidal coordination
environments is reported. The degree of distortion as well as
the overall symmetry of the molecules varies among the
members of the series. Different experimental procedures
resulted in the isolation of solvomorphs (pseudopolymorphs
with different solvent content) for some of the family
members. Importantly, their disparate packing arrangements
lead to very different dynamic magnetic behavior. The results
of magnetostructural correlations and ab initio calculations
reveal that the deciding factor for SMM behavior is not the degree of distortion which, a priori, would be expected to be the case,
but rather the interactions between neighboring molecules in the solid state. | |
| dc.description | Department of Energy, Basic Energy Sciences, Materials
Sciences Division
Robert A. Welch Foundation for financial support
Ciencia y Tecnología del Distrito Federal (ICyTDF)
Spanish Ministerio de Economía y Competitividad | |
| dc.language | eng | |
| dc.publisher | Journal Of the American Chemical Society | |
| dc.rights | embargoedAccess | |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.rights | embargoedAccess | |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject | SMM behavior | |
| dc.subject | distorted trigonal bipyramidal | |
| dc.subject | mononuclear CoII complexes | |
| dc.title | Relaxation Dynamics of Identical Trigonal Bipyramidal Cobalt Molecules with Different Local Symmetries and Packing Arrangements: Magnetostructural Correlations and ab inito Calculations | |
| dc.type | Artículo | |
