Articulo
Phase-Separation Perspective on Dynamic Heterogeneities in Glass-Forming Liquids
Registro en:
issn:1079-7114
issn:0031-9007
Autor
Cammarota, Chiara
Cavagna, Andrea
Giardina, Irene
Gradenigo, Giacomo
Grigera, Tomás Sebastián
Parisi, Giorgio
Verrocchio, Paolo
Institución
Resumen
We study dynamic heterogeneities in a model glass former whose overlap with a reference configuration is constrained to a fixed value. We find that the system phase separates into regions of small and large overlap, indicating that a nonzero surface tension plays an important role in the formation of dynamical heterogeneities. We calculate an appropriate thermodynamic potential and find evidence of a Maxwell construction consistent with a spinodal decomposition of two phases. Our results suggest that even in standard, unconstrained systems dynamic heterogeneities are the expression of an ephemeral phase-separating regime ruled by a finite surface tension. Facultad de Ciencias Exactas Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas