Obtención de carbonato de glicerol a partir de glicerol y CO2 empleando óxidos de La y La/Zr

dc.contributorVelasquéz Márquez, León Mauricio
dc.contributorEstado Sólido y Catálisis Ambiental
dc.creatorQuiroga Mateus, William Andrés
dc.date.accessioned2023-06-01T15:10:41Z
dc.date.accessioned2023-06-06T23:19:59Z
dc.date.available2023-06-01T15:10:41Z
dc.date.available2023-06-06T23:19:59Z
dc.date.created2023-06-01T15:10:41Z
dc.date.issued2023
dc.identifierhttps://repositorio.unal.edu.co/handle/unal/83943
dc.identifierUniversidad Nacional de Colombia
dc.identifierRepositorio Institucional Universidad Nacional de Colombia
dc.identifierhttps://repositorio.unal.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/6651229
dc.description.abstractEn este trabajo de investigación se realizó inicialmente una revisión del estado del arte sobre la reacción de carboxilación directa entre el glicerol y el CO2 para la obtención de carbonato de glicerol, abarcando aspectos como las problemáticas ambientales, la naturaleza de los catalizadores empleados, limitaciones cinéticas y termodinámicas. Posteriormente, óxidos de La y La/Zr fueron sintetizados por el método de coprecipitación convencional y caracterizados evaluando sus propiedades fisicoquímicas para luego ser empleados en dicha reacción. Adicionalmente, se realizó un estudio sobre los parámetros que afectan la reacción como el efecto del agua, temperatura, presión, tiempo, agente desecante y masa de catalizador. Finalmente, los resultados obtenidos ilustran que el catalizador de La/Zr es promisorio para la producción de este compuesto de alto interés industrial debido a la correlación entre su capacidad de captura y liberación de CO2 junto a su actividad catalítica. (Texto tomado de la fuente)
dc.description.abstractIn this research work, a review of the state of the art on the direct carboxylation reaction between glycerol and CO2 to obtain glycerol carbonate was mainly carried out, covering aspects such as environmental problems, the nature of the catalysts used, kinetic and thermodynamics limitations. Subsequently, the oxides of La and La/Zr were synthesized by the conventional coprecipitation method and characterized by evaluating their physicochemical properties to later be used in this reaction. Additionally, a study was carried out on the parameters that flourish the reaction such as the effect of water, temperature, pressure, time, drying agent and catalyst mass. Finally, the results obtained illustrate that the La/Zr catalyst is promising for the production of this compound of high industrial interest due to the connection between its capacity to capture and release CO2 together with its catalytic activity.
dc.languagespa
dc.publisherUniversidad Nacional de Colombia
dc.publisherBogotá - Ciencias - Maestría en Ciencias - Química
dc.publisherFacultad de Ciencias
dc.publisherBogotá, Colombia
dc.publisherUniversidad Nacional de Colombia - Sede Bogotá
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dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleObtención de carbonato de glicerol a partir de glicerol y CO2 empleando óxidos de La y La/Zr
dc.typeTrabajo de grado - Maestría


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