"Green-emitting Eu-activated powders were produced by a two-stage method consisting of pressure-assisted combustion synthesis and postannealing in ammonia. The as-synthesized powders exhibited a red photoluminescence (PL) peak located at λ = 616 nm when excited with λ = 395 nm UV. This emission peak corresponds to the ⁵D₀ → ⁷F₂ transition in Eu³⁺. After annealing in ammonia, the PL emission changed to an intense broad-band peak centered at λ = 500 nm, most likely produced by 4f⁶5d¹ → 4f⁷ electronic transitions in Eu²⁺. This green-emitting phosphor has excitation band in the near UV-blue region (λ = 300–450 nm). Xray diffraction analysis reveals mainly the orthorhombic EuAlO₃ and Al<sub>2</sup>O₃ phases. Transmission electron microscopy observations showed that the grains are formed by faceted nanocrystals (∼4 nm) of polygonal shape. The excellent excitation and emission properties make these powders very promising to be used as phosphors in UV solid-state diodes coupled to activate white-emitting lamps."