Unusual Hofmann elimination under mild conditions in polymerizable cationic surfactant systems

dc.contributorJim�nez, R.M., Departamento de Ingenieria Quimica, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; Soltero, J.F.A., Departamento de Ingenieria Quimica, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; Manr�quez, R., Depto. de Madera, Celulosa y Papel, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; L�pez-Dellamary, F.A., Depto. de Madera, Celulosa y Papel, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; Palacios, G., Departamento de Qu�mica, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; Puig, J.E., Departamento de Ingenieria Quimica, Universidad de Guadalajara, Boulevard M. Garcia Barragan #1451, Guadalajara, Jalisco 44430, Mexico; Morini, M., Depto. de Quim. de Ingenieria Quim., Universidad Nacional del Sur, Bahia Blanca 8000, Argentina; Schulz, P.C., Depto. de Quim. de Ingenieria Quim., Universidad Nacional del Sur, Bahia Blanca 8000, Argentina
dc.creatorJimenez, R.M.
dc.creatorSoltero, J.F.A.
dc.creatorManriquez, R.
dc.creatorLopez-Dellamary, F.A.
dc.creatorPalacios, G.
dc.creatorPuig, J.E.
dc.creatorMorini, M.
dc.creatorSchulz, P.C.
dc.date.accessioned2015-09-15T19:15:37Z
dc.date.accessioned2022-11-02T14:17:23Z
dc.date.available2015-09-15T19:15:37Z
dc.date.available2022-11-02T14:17:23Z
dc.date.created2015-09-15T19:15:37Z
dc.date.issued2002
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0037076628&partnerID=40&md5=027873b12cb76b813ef61cca3242cf1e
dc.identifierhttp://dx.doi.org/10.1021/la011077j
dc.identifierhttp://hdl.handle.net/20.500.12104/45555
dc.identifier10.1021/la011077j
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4994898
dc.description.abstractHofmann elimination and nucleophilic substitution reactions have been simultaneously observed at relatively low temperatures in a family of polymerizable alkyltrimethylammonium methacrylate surfactants, as well as in dodecyltrimethylammonium hydroxide. In concentrated aqueous solutions of the latter surfactant, Hofmann elimination occurs at room temperature. These reactions have been verified by IR, 1H NMR, and 13C NMR spectroscopies; differential scanning calorimetry; gas chromatography coupled to mass spectroscopy; and other techniques. A possible explanation of this phenomenon is provided.
dc.relationScopus
dc.relationChemAbsS
dc.relationWOS
dc.relationLangmuir
dc.relation18
dc.relation10
dc.relation3767
dc.relation3772
dc.titleUnusual Hofmann elimination under mild conditions in polymerizable cationic surfactant systems
dc.typeArticle


Este ítem pertenece a la siguiente institución