Photoinduced electron-transfer cycloreversion of thietanes: The role of ion-molecule complexes

Argüello, Juan Elias; Pérez-Ruiz, Raúl; Miranda, Miguel A.

info:eu-repo/semantics/article

Fecha

2010-04

Registro en:

Argüello, Juan Elias; Pérez-Ruiz, Raúl; Miranda, Miguel A.; Photoinduced electron-transfer cycloreversion of thietanes: The role of ion-molecule complexes; American Chemical Society; Organic Letters; 12; 8; 4-2010; 1884-1887

1523-7060

http://hdl.handle.net/11336/70441

1523-7052

CONICET Digital

CONICET

https://repositorioslatinoamericanos.uchile.cl/handle/2250/4389889

Autor

Argüello, Juan Elias

Pérez-Ruiz, Raúl

Miranda, Miguel A.

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

Cycloreversion (CR) of thietane radical cations leads to formation of thiobenzophenone and the corresponding alkenes, eventually followed by secondary [4 + 2] cycloaddition. Final product distribution depends on the ability of fragments to escape from ion-molecule complexes (IMCs).

Materias

electron transfer

photochemistry

thietanes

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