info:eu-repo/semantics/article
Design-Considerations regarding Silicon/Graphite and Tin/Graphite Composite Electrodes for Lithium-Ion Batteries
Fecha
2018-12Registro en:
Otero, Manuel; Heim, Christopher; Leiva, Ezequiel Pedro M.; Wagner, Norbert; Friedrich, Andreas; Design-Considerations regarding Silicon/Graphite and Tin/Graphite Composite Electrodes for Lithium-Ion Batteries; Nature Publishing Group; Scientific Reports; 8; 1; 12-2018
2045-2322
CONICET Digital
CONICET
Autor
Otero, Manuel
Heim, Christopher
Leiva, Ezequiel Pedro M.
Wagner, Norbert
Friedrich, Andreas
Resumen
An analytical model is proposed to investigate properties of composite electrodes that utilize more than one active material. We demonstrate how the equations can be applied to aid in the design of electrodes by comparing silicon-graphite and tin-graphite composite negative electrodes as examples with practical relevance. Based on simple assumptions, the results show how volume expansion tolerance and initial porosity are important factors for the achievable gravimetric and volumetric capacities as well as volumetric energy density. A Si-alloy/graphite composite electrode is used as an experimental system to corroborate the formulated analysis. Kinetic limitations are also addressed based on a novel heuristic approach.