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Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography

Fecha
2020-02
Registro en:
Reguera, Mónica Beatriz; Galante, Nadia Soledad; Varela, Noelia Melina; Profeta, Mariela Inés; Jorge, Maria Josefa; et al.; Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography; Gupta Publications; International Journal of Chemistry Studies; 4; 1; 2-2020; 52-55
2581-348X
CONICET Digital
CONICET
Autor
Reguera, Mónica Beatriz
Galante, Nadia Soledad
Varela, Noelia Melina
Profeta, Mariela Inés
Jorge, Maria Josefa
Jorge, Lilian Cristina
Romero, Jorge Marcelo
Jorge, Nelly Lidia
Institución
Resumen
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied to obtain activation parameters.(DH#=13.07 ± 0.7 Kcal mol-1; DS#=-40,28 ± 0.4calmol-1 K-1; DG#=35.07 ± 0.7 Kcal mol-1) in the 453 – 553 K temperature range.
Materias

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