STUDY OF THE INTERACTIONS BETWEEN COPPER(II) ACETATE MONOHYDRATE AND OROTIC ACID AND OROTATE LIGANDS

dc.creatorSEGUEL,GLORIA V
dc.creatorRIVAS,BERNABÉ L
dc.creatorPAREDES,CÉSAR
dc.date2010-01-01
dc.date.accessioned2017-03-07T16:31:46Z
dc.date.available2017-03-07T16:31:46Z
dc.identifierhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000300018
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/403072
dc.descriptionDifferent complexes by reacting copper(II) acetate monohydrate with orotic acid and orotate as ligands were prepared. These compounds were characterized by elemental analysis, spectroscopy, and thermal analysis. It is suggested that in both compounds, the Cu2(acetate)4 suffers the break of both acetate groups by a substitution of orotic or orotate ligands, increasing the Cu-Cu distance. It was corroborated by the magnetic moment values of 1.65 and 1.82 B.M for these compounds. The anion orotato(-1) coordinates through the carboxylic acid and the orotic acid by the oxygen from exocyclic C=O. Semiempirical PM3 calculations for both compounds were also carried out.
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.sourceJournal of the Chilean Chemical Society v.55 n.3 2010
dc.subjectCopper(II)
dc.subjectacetate
dc.subjectmetal acetate
dc.subjectorotic acid
dc.subjectsemi-empirical calculations
dc.titleSTUDY OF THE INTERACTIONS BETWEEN COPPER(II) ACETATE MONOHYDRATE AND OROTIC ACID AND OROTATE LIGANDS
dc.typeArtículos de revistas


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