p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE

dc.creatorCHORDIA,LEENA
dc.creatorCHATURVEDI,ALOK
dc.date2008-12-01
dc.date.accessioned2017-03-07T16:08:42Z
dc.date.available2017-03-07T16:08:42Z
dc.identifierhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400002
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/396844
dc.descriptionp-Nitrophenyl and p-nitrobenzoyl derivatives of 0,0'-alkylene dithiophosphate, OGOP(S)SC6H4N0(2) and OGOP(S)SCOC6H4N0(2) (Where G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2CHMe-) have been synthesized by the reactions of p-bromo nitrobenzene / p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphoric acids. These derivatives are yellow and red coloured solids, respectively and are soluble in common organic solvents. These are characterized by elemental analysis, IR and NMR ('H and 31P) spectral studies. In contrast to the bi-dentate chelating behaviour of the ligand in the metal and organometal derivatives of alkylene dithiophosphates, the behaviour of dithiophosphato moiety in these derivatives is found to be mono-dentate in nature.
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.sourceJournal of the Chilean Chemical Society v.53 n.4 2008
dc.subject- p-Bromo nitrobenzene
dc.subjectp-nitrobenzoyl chloride
dc.subjectammonium salt of alkylene dithiophosphoric acids
dc.titlep-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF 0,0' - ALKYLENE DITHIOPHOSPHATE
dc.typeArtículos de revistas


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