Why silver deposition is so fast: Solving the enigma of metal deposition

dc.contributorUlm University
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorLehrstuhl für Theoretische Chemie
dc.contributorUniversidad Nacional Del Litoral
dc.contributorUniversidad Nacional de Cõrdoba
dc.date.accessioned2014-05-27T11:29:58Z
dc.date.accessioned2022-10-05T18:55:14Z
dc.date.available2014-05-27T11:29:58Z
dc.date.available2022-10-05T18:55:14Z
dc.date.created2014-05-27T11:29:58Z
dc.date.issued2013-07-22
dc.identifierAngewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.
dc.identifier1433-7851
dc.identifier1521-3773
dc.identifierhttp://hdl.handle.net/11449/76014
dc.identifier10.1002/anie.201301998
dc.identifierWOS:000321896800057
dc.identifier2-s2.0-84880359340
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3924920
dc.description.abstractA perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.languageeng
dc.relationAngewandte Chemie - International Edition
dc.relation12.102
dc.relation6,155
dc.relation6,155
dc.rightsAcesso restrito
dc.sourceScopus
dc.subjectcorrosion
dc.subjectmetal deposition
dc.subjecttheoretical electrochemistry
dc.subjectElectrochemical reactions
dc.subjectMD simulation
dc.subjectMetal deposition
dc.subjectPerfect matches
dc.subjectSilver deposition
dc.subjectSolvation energy
dc.subjectStrong interaction
dc.subjectCatalysis
dc.subjectChemistry
dc.subjectCorrosion
dc.subjectDeposition
dc.titleWhy silver deposition is so fast: Solving the enigma of metal deposition
dc.typeArtigo


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