KINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM

dc.creatorHUO,SHUYING
dc.creatorSONG,CHANGYING
dc.creatorHUAN,SHANJIN
dc.creatorSHEN,SHIGANG
dc.creatorSUN,HANWEN
dc.date2007-03-01
dc.date.accessioned2017-03-07T15:48:04Z
dc.date.available2017-03-07T15:48:04Z
dc.identifierhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000100011
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/391064
dc.descriptionThe oxidation of 6-Aminocaproic acid by Ag(III) complex, dihydroxydiperiodatoargentate(III) (DPA), was studied in alkaline medium. The reaction was first order with respect to Ag(III) complex, and the order with respect to 6-aminocaproic acid was from one to two. A plausible mechanism involving a pre-equilibrium of adduct formation between the complex and reductant was proposed form the kinetics study. The rate equations derived from mechanism can explain all experimental phenomena, and the activation parameters along with rate constants of the rate-determining step were calculated
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.sourceJournal of the Chilean Chemical Society v.52 n.1 2007
dc.subjectdihydroxydiperiodatoargentate (III)
dc.subject6-aminocaproic acid
dc.subjectredox reaction
dc.subjectkinetics and mechanism
dc.titleKINETICS AND MECHANISM OF OXIDATION OF 6-AMINOCAPROIC ACID BY DIHYDROXYDIPERIODATOA RGENTATE (III) IN ALKALINE MEDIUM
dc.typeArtículos de revistas


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