HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES

dc.creatorBARICELLI,P.J.
dc.creatorLUJANO,R.E.
dc.creatorMEDINA,L.
dc.creatorLONGO,C.
dc.creatorPARDEY,A.J.
dc.creatorPASTENE,R.
dc.creatorMOYA,S.A.
dc.date2000-09-01
dc.date.accessioned2017-03-07T15:08:25Z
dc.date.available2017-03-07T15:08:25Z
dc.identifierhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/378674
dc.descriptionIn the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carried out in an autoclave (Parr, 100 mL), 10 atm, CO/H2 = 1 and ratio catalyst/substrate 1/100. Preliminary kinetics parameters show a high catalytic activity of these complexes to the formation of methanol and methyl formate
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.sourceBoletín de la Sociedad Chilena de Química v.45 n.3 2000
dc.subjecthydroformylation
dc.subjectformaldehyde
dc.subjectrhodium complexes
dc.subjectmethyl formate
dc.titleHOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
dc.typeArtículos de revistas


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