Study of the reactive distillation in the production of isobutyl acetate

dc.contributorRodriguez Niño, Gerardo
dc.contributorOrjuela Londoño, Alvaro
dc.contributorDepartamento de Ingeniería Química y Ambiental
dc.contributorProcesos Químicos y Bioquímicos
dc.creatorMartínez Arias, Andrés Felipe
dc.date.accessioned2020-09-01T02:34:19Z
dc.date.available2020-09-01T02:34:19Z
dc.date.created2020-09-01T02:34:19Z
dc.date.issued2020-01-02
dc.identifierhttps://repositorio.unal.edu.co/handle/unal/78345
dc.description.abstractThis work presents a study of a reactive distillation process for the production of Isobutyl acetate, from the fundamentals of the operation like the phase equilibria and the reaction kinetics, to the conceptual design. Experimental phase equilibrium data was evaluated, and the quaternary mixture interactions were accurately described using an activity coefficients model for the liquid phase, and a viral equation of state for the vapor phase as described in Chapter one. In Chapter two a mole-based kinetic expression was adjusted to describe the esterification process using an heterogeneous catalyst. Then, a conceptual design of the reactive distillation process, coupling the phase equilibria and the reaction kinetics, was done in order to obtain a suitable configuration for an industrial scale process to produce Isobutyl acetate. Finally, rigorous simulations and optimization enabled to obtain the best operating conditions of the reactive distillation process for isobutyl acetate production at the industrial scale presented in Chapter three.
dc.description.abstractEste trabajo presenta un estudio del proceso de producción de Isobutil acetato por medio de destilación reactiva, desde los fundamentos de la operación como el equilibrio de fases y la cinética de reacción, hasta el diseño conceptual. Se evaluó información experimental del equilibrio de fases y las interacciones de la mezcla cuaternaria se describieron adecuadamente usando un modelo de coeficientes de actividad para la fase liquida y una ecuación de estado para la fase vapor. Una expresión cinética con base en fracciones molares fue desarrollada para describir el proceso de esterificación usando un catalizador heterogéneo. Posteriormente, se desarrolló el diseño conceptual del proceso de destilación reactiva empleando simultáneamente el equilibrio de fases y la cinética previamente obtenidos. Finalmente, con base en simulación rigurosa y optimización del proceso de destilación reactiva se obtuvieron las condiciones de operación masa adecuadas para la producción de Isobutil acetato por destilación reactiva a escala industria
dc.languageeng
dc.publisherBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.publisherUniversidad Nacional de Colombia - Sede Bogotá
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dc.rightsAtribución-SinDerivadas 4.0 Internacional
dc.rightsAcceso abierto
dc.rightshttp://creativecommons.org/licenses/by-nd/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsDerechos reservados - Universidad Nacional de Colombia
dc.titleStudy of the reactive distillation in the production of isobutyl acetate
dc.typeOtro


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