Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas

dc.contributorGodoy Silva, Rubén Darío
dc.contributorRodríguez Varela, Luis Ignacio
dc.creatorPasos Panqueva, Johan Andrés
dc.date.accessioned2021-08-18T15:15:12Z
dc.date.available2021-08-18T15:15:12Z
dc.date.created2021-08-18T15:15:12Z
dc.date.issued2021-06
dc.identifierhttps://repositorio.unal.edu.co/handle/unal/79961
dc.identifierUniversidad Nacional de Colombia
dc.identifierRepositorio Institucional Universidad Nacional de Colombia
dc.identifierhttps://repositorio.unal.edu.co/
dc.description.abstractMúltiples estudios presentan las microalgas como la fuente de biocombustibles más prometedora, debido a que, entre otras características, son 50 veces más eficientes en convertir la luz solar en biomasa y capturan entre 10 y 50 veces más CO2 que las plantas terrestres. Debido a que el contenido de agua de estos microorganismos puede alcanzar más del 95% en peso, la licuefacción hidrotermal (LHT), que emplea agua a condiciones supercríticas, se ha perfilado como la mejor manera para convertir la biomasa húmeda de microalga en biocrudo. Sin embargo, el rendimiento del proceso para producir biocrudo no supera el 50%, por lo que la generación de una fase acuosa (subproducto de la LHT) constituye el principal residuo del proceso. El presente trabajo pretende evaluar otro proceso hidrotermal, denominado oxidación hidrotermal con peróxido, como alternativa de tratamiento de la fase acuosa proveniente de la LHT de la microalga Chlorella vulgaris. En primer lugar, se obtuvo la biomasa algal a licuar, se caracterizó bioquímicamente y se realizó la licuefacción hidrotermal, determinando los rendimientos de producción de cada una de las fases a condiciones constantes de reacción (375ºC y 15 minutos de reacción). Posteriormente se caracterizó la fase acuosa obtenida y se diseñó un plan de experimentos que permita establecer las condiciones de reacción adecuadas (tiempo y relación molar de peróxido) que maximicen la producción de fase acuosa tratada. Finalmente, se caracterizó la fase acuosa tratada y se realizaron cultivos comparativos de la microalga en diferentes diluciones de fase acuosa, con el fin de cuantificar el crecimiento algal y evaluar el potencial de recirculación del agua tratada por medio de la oxidación hidrotermal con peróxido. Con el desarrollo de este trabajo se demostró que es viable tratar la fase acuosa de la LHT, para recircular agua y recuperar nutrientes; con lo cual, se mejora la sostenibilidad ambiental y energética de la producción de biocrudo a partir de algas. (Texto tomado de la fuente)
dc.description.abstractMultiple studies present microalgae as the most promising source of biofuels, due to the fact that, among other characteristics, they are 50 times more efficient in converting sunlight into biomass and capture between 10 and 50 times more CO2 than terrestrial plants. Because the water content of these microorganisms can reach more than 95% by weight, hydrothermal liquefaction (LHT), which uses water at supercritical conditions, has emerged as the best way to convert wet microalgae biomass to biocrude. However, the yield of the process to produce biocrude does not exceed 50%, so the generation of an aqueous phase (by-product of the LHT) constitutes the main waste of the process. The present work aims to evaluate another hydrothermal process, called hydrothermal oxidation with peroxide, as an alternative for treating the aqueous phase from the LHT of the microalgae Chlorella vulgaris. First, the algal biomass to be liquefied was obtained, it was biochemically characterized and hydrothermal liquefaction was carried out, determining the production yields of each of the phases at constant reaction conditions (375ºC and 15 minutes of reaction). Subsequently, the aqueous phase obtained was characterized and an experiment plan was designed to establish the appropriate reaction conditions (time and molar ratio of peroxide) that maximize the production of the treated aqueous phase. Finally, the treated aqueous phase was characterized and comparative cultures of the microalgae were carried out in different dilutions of the aqueous phase, in order to quantify the algal growth and evaluate the recirculation potential of the treated water by means of hydrothermal oxidation with peroxide. With the development of this work it was demonstrated that it is feasible to treat the aqueous phase of the LHT, to recirculate water and recover nutrients; with which, the environmental and energy sustainability of the production of biocrude from algae is improved.(Text taken from the source)
dc.languagespa
dc.publisherUniversidad Nacional de Colombia
dc.publisherBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.publisherFacultad de Ingeniería
dc.publisherBogotá - Colombia
dc.publisherUniversidad Nacional de Colombia - Sede Bogotá
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dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsDerechos reservados al autor, 2021
dc.titleEvaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
dc.typeTrabajo de grado - Maestría


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