dc.contributor | Pérez Flórez, Alejandro | |
dc.contributor | Ramírez Franco, José Herney | |
dc.contributor | Investigación en Tecnología Ambiental y de Materiales | |
dc.creator | Meneses Madroñero, Paula Stefania | |
dc.date.accessioned | 2022-08-30T16:51:49Z | |
dc.date.available | 2022-08-30T16:51:49Z | |
dc.date.created | 2022-08-30T16:51:49Z | |
dc.date.issued | 2022 | |
dc.identifier | https://repositorio.unal.edu.co/handle/unal/82198 | |
dc.identifier | Universidad Nacional de Colombia | |
dc.identifier | Repositorio Institucional Universidad Nacional de Colombia | |
dc.identifier | https://repositorio.unal.edu.co/ | |
dc.description.abstract | El desarrollo de nuevas tecnologías, permiten el control de sustancias químicas peligrosas presentes en los efluentes de diversas industrias o recintos educativos, cuya remoción no es factible por métodos convencionales. Asimismo, el aumento en el número de vehículos cada año es mayor y esto está generando residuos como el caucho de las llantas. En esta investigación se emplea el caucho de llanta como materia prima para producir carbón activado que se usa como soporte de óxidos metálicos de Fe, Cu, Mn y una mezcla de los dos mejores metales analizados (CuMn), estos catalizadores son preparados por medio del método de impregnación húmeda y caracterizados por XRD, SEM-EDX, TPR-H2, FTIR y propiedades texturales. Los sólidos se evaluaron mediante la oxidación húmeda catalítica con aire de un efluente contaminado con colorantes de tinción de Gram a condiciones ambientales de reacción: 25 °C, presión atmosférica. y flujo de aire de 2 mL/min. Los resultados experimentales indicaron porcentajes de remoción del 98%, eliminación de DQO del 33% en tan solo 3 horas de reacción y conversión del carbono orgánico total (COT) del 80% a las 24 horas de reacción. El catalizador de Cu con una relación másica del 5% demostró ser el catalizador con mayor actividad catalítica. (Texto tomado de la fuente) | |
dc.description.abstract | The development of new technologies allows the control of dangerous chemical substances present in the water currents of various industries or educational facilities, whose removal is not feasible by conventional methods. Similarly, the increase in the number of motor vehicles is greater each year and this is generating waste such as tire rubber. In this research, tire rubber is use as a raw material to produce activated carbon that is use as a support for metal oxides of Fe, Cu, Mn and a mixture of the two best metals analyzed (CuMn), these catalysts are prepared by means of the wet impregnation method and characterized by XRD, SEM-EDX, TPR-H2, FTIR and textural properties. Water contaminated with Gram stain dyes was treated with the synthesized solids by catalytic wet oxidation with air under ambient conditions: 25°C, atmospheric pressure and air flow of 2 mL/min. The experimental results indicated percentages of colorant removal of 98%, COD elimination of 33% in only 3 hours of reaction and conversion of total organic carbon (COT) of 80% at 24 hours of reaction. The Cu catalyst with a mass ratio of 5% proved to be the catalyst with the highest catalytic activity. | |
dc.language | spa | |
dc.publisher | Universidad Nacional de Colombia | |
dc.publisher | Bogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química | |
dc.publisher | Departamento de Ingeniería Química y Ambiental | |
dc.publisher | Facultad de Ingeniería | |
dc.publisher | Bogotá, Colombia | |
dc.publisher | Universidad Nacional de Colombia - Sede Bogotá | |
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dc.rights | Atribución-SinDerivadas 4.0 Internacional | |
dc.rights | http://creativecommons.org/licenses/by-nd/4.0/ | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Remoción de colorantes presentes en aguas reales provenientes de un laboratorio de microbiología mediante el proceso CWAO con un catalizador Mn, Cu, y/o Fe soportado en carbón activado a partir de caucho de llanta | |
dc.type | Trabajo de grado - Maestría | |