Chile
| artículo
Rhodium(I) diolefin complexes with polycyclic π-arene ligands. Synthesis of bimetallic complexes with diphenylmethane as bridging ligand
| dc.creator | Valderrama Guerrero, Mauricio | |
| dc.creator | Scotti Radich, Mario | |
| dc.creator | Cifuentes, Pedro | |
| dc.creator | Ganz, Ricardo | |
| dc.date.accessioned | 2019-12-28T02:45:29Z | |
| dc.date.available | 2019-12-28T02:45:29Z | |
| dc.date.created | 2019-12-28T02:45:29Z | |
| dc.date.issued | 1984 | |
| dc.identifier | 10.1007/BF00618172 | |
| dc.identifier | https://repositorio.uc.cl/handle/11534/27131 | |
| dc.identifier | http://link.springer.com/article/10.1007/BF00618172 | |
| dc.description.abstract | The preparation and properties of cationic arenerhodium(I) complexes of general formula [Rh(diolefin)(?6arene)]ClO4 (diolefin=1,5-cyclooctadiene, tetrafluorobenzobarrelene or trimethyltetrafluorobenzobarrelene; arene = biphenyl or diphenylmethane) are described. These complexes react with the solvated intermediate complex [Rh(diolefin)(Me2CO)x]ClO4 to give homobimetallic [(diolefin)Rh(Ph2CH2)Rh(diolefin)](ClO4)2 derivatives. New heterobimetallic complexes of the type [(diolefin)Rh(Ph2CH2)Cr(CO)3]ClO4 have been synthesized by reaction of Cr(CO)3(?6-Ph2CH2) with the solvated complex [Rh(diolefin)(Me2CO)x]ClO4 or, alternatively by treatment of [Rh(diolefin)(?6-arene)]ClO4 with the complex Cr(CO)3(?6Me3B3N3Me3) in chloroform solution. | |
| dc.language | en | |
| dc.rights | acceso restringido | |
| dc.title | Rhodium(I) diolefin complexes with polycyclic π-arene ligands. Synthesis of bimetallic complexes with diphenylmethane as bridging ligand | |
| dc.type | artículo |