Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes

dc.creatorValderrama Guerrero, Mauricio
dc.creatorGanz, Ricardo
dc.creatorSariego, Renato
dc.date.accessioned2019-12-28T02:45:24Z
dc.date.available2019-12-28T02:45:24Z
dc.date.created2019-12-28T02:45:24Z
dc.date.issued1983
dc.identifier10.1007/BF00956025
dc.identifierhttps://repositorio.uc.cl/handle/11534/27113
dc.identifierhttp://link.springer.com/article/10.1007/BF00956025
dc.description.abstractThe preparation and properties of cationic rhodium(I) complexes of the types [Rh(Me3TFB)L2]PF6 (L=O. N. P, As or Sb-donor ligands, Me3TFB=trimethyltetrafluorobarrelene), [Rh(Me3TFB) (?6-arene)]PF6 (arene=C6Me6, C6H6Me3, C6H6 or C10H8) and [Rh(Me23TFB)(PPh3)L]PF6 (L=Me2CO or Me2SO) are described. Some complexes react with carbon monoxide at normal pressure with displacement of Me3TFB and formation of carbonyl derivatives. The arene-exchange behaviour for the new complex with naphthalene (C10H8) was examined in acetone solutions.
dc.languageen
dc.rightsacceso restringido
dc.titleSynthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes
dc.typeartículo


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