Artículo
Plasmonic Sensing of Aqueous-Divalent Metal Ions by Biogenic Gold Nanoparticles
Autor
SILVA DE HOYOS, LUISA ELENA; 373046
Sánchez Mendieta, Víctor ; 13230
VILCHIS NESTOR, ALFREDO RAFAEL; 161073
CAMACHO LOPEZ, MIGUEL ANGEL; 122933
Trujillo Reyes, Jesica; 212986
AVALOS BORJA, MIGUEL; 116
SILVA DE HOYOS, LUISA ELENA
Sánchez Mendieta, Víctor
VILCHIS NESTOR, ALFREDO RAFAEL
CAMACHO LOPEZ, MIGUEL ANGEL
Trujillo Reyes, Jesica
AVALOS BORJA, MIGUEL
Institución
Resumen
Research Article Plasmonic Sensing of Aqueous-Divalent Metal Ions by Biogenic Gold Nanoparticles The chemical interaction between biogenic gold nanoparticles (AuNPs) and several metal (II) ions can be regarded as a practical, twofold, colorimetric, and plasmon resonance sensing method for the recognition of some divalent metal ions in aqueous solutions. The green synthesized AuNPs, using Camellia sinensis as a reducing agent, were characterized by a surface plasmon resonance (SPR) using UV-Vis spectroscopy, infrared spectroscopy, and transmission electron microscopy. The AuNP colloidal solutions obtained have a pink-reddish color with SPRs centered between 529 and 536 nm. AuNPs with spherical, triangular, and hexagonal shapes were found by TEM analyses. Despite their divergent morphologies, these AuNPs can be employed as colorimetric and plasmon resonance sensors for detection of Ca2+, Sr2+, Cu2+, and Zn2+, primarily, in aqueous solutions. Sensibility studies based on molar concentrations were also performed for these metal ions. Furthermore, solid biogenic AuNPs/cellulosic biocomposites were prepared with the aim of developing portable, fast, and dependable colorimetric sensors; nevertheless, these biocomposites resulted to be good adsorbent materials of metal ions.