| dc.creator | woods, Toby James | |
| dc.creator | Ballesteros-Rivas, Maria fernanda | |
| dc.creator | Ostrovsky, S M. | |
| dc.creator | Palii, A. V. | |
| dc.creator | Reu, O. S | |
| dc.creator | Klokishner, s. I | |
| dc.creator | Dunbar, Kim Renee | |
| dc.date | 2018-02-16T20:50:02Z | |
| dc.date | 2018-02-16T20:50:02Z | |
| dc.date | 2015-06-12 | |
| dc.date.accessioned | 2019-05-28T21:36:26Z | |
| dc.date.available | 2019-05-28T21:36:26Z | |
| dc.identifier | 1521-3765 | |
| dc.identifier | http://hdl.handle.net/20.500.11799/68665 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/2904618 | |
| dc.description | artículo científico | |
| dc.description | The ligand-centered radical complex [(CoTPMA)2-μ-bmtz.−](O3SCF3)3⋅CH3CN (bmtz=3,6-bis(2′-pyrimidyl)-1,2,4,5-tetrazine, TPMA=tris-(2-pyridylmethyl)amine) has been synthesized from the neutral bmtz precursor. Single-crystal X-ray diffraction studies have confirmed the presence of the ligand-centered radical. The CoII complex exhibits slow paramagnetic relaxation in an applied DC field with a barrier to spin reversal of 39 K. This behavior is a result of strong antiferromagnetic metal–radical coupling combined with positive axial and strong rhombic anisotropic contributions from the CoII ions. | |
| dc.description | National Science Foundation
Ciencia y Tecnolog a del Distrito Federal (ICyTDF)
STCU | |
| dc.language | eng | |
| dc.publisher | Wiley VCH | |
| dc.relation | 21, 10302-10305; | |
| dc.rights | embargoedAccess | |
| dc.rights | No aplica | |
| dc.rights | embargoedAccess | |
| dc.rights | No aplica | |
| dc.title | Strong Direct Magnetic Coupling in a Dinuclear CoII Tetrazine Radical Single-Molecule Magnet. | |
| dc.type | Artículos de revistas | |
