Oxidation and catalytic properties of a binuclear copper(I) complex with a meta-xylyl spacer ligand

dc.creatorCalero, Rolando
dc.creatorVega, Andrés
dc.creatorGarcía, Ana María
dc.creatorSpodine Spiridonova, Evgenia
dc.creatorManzur Saffie, Jorge
dc.date.accessioned2018-12-20T15:20:37Z
dc.date.available2018-12-20T15:20:37Z
dc.date.created2018-12-20T15:20:37Z
dc.date.issued2003
dc.identifierBoletin de la Sociedad Chilena de Quimica, Volumen 48, Issue 2, 2018, Pages 85-88
dc.identifier03661644
dc.identifierhttps://repositorio.uchile.cl/handle/2250/158842
dc.description.abstractThe oxidation product of the binuclear copper (I) complex Cu2L(CIO4)2 (L = N,N′-bis-(6-methyl-2-pyridil) (2′-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, [Cu2L(Me-O)2](CIO4)2, the metal centres are bridged by two methoxide groups, and the oxygenation of the xylyl spacer of the hexadentate ligand is not observed. The copper(I) complex was found to be a catalyst for the oxidation of 3,5-ditertbutylcatechol to 3,5-ditertbutyl-o-benzoquinone by molecular oxygen.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceBoletin de la Sociedad Chilena de Quimica
dc.subjectCatalysis
dc.subjectDimeric copper complexes
dc.subjectOxidation
dc.titleOxidation and catalytic properties of a binuclear copper(I) complex with a meta-xylyl spacer ligand
dc.typeArtículo de revista


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