Ruthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of N-benzylideneaniline hydrogenation

dc.creatorMoya, S.
dc.creatorVidal, M.
dc.creatorBrown, K.
dc.creatorNegrete-Vergara, C.
dc.creatorAbarca, G.
dc.creatorAguirre, P.
dc.date.accessioned2018-12-20T15:10:24Z
dc.date.available2018-12-20T15:10:24Z
dc.date.created2018-12-20T15:10:24Z
dc.date.issued2012
dc.identifierInorganic Chemistry Communications, Volumen 22, 2012, 146-148.
dc.identifier13877003
dc.identifier10.1016/j.inoche.2012.05.047
dc.identifierhttps://repositorio.uchile.cl/handle/2250/158162
dc.description.abstractThe synthesis and characterization of ruthenium complexes containing polypyridine ligands: Ru(dppz)(PPh3)(2)Cl-2. Ru(bpy)(PPh3)(2)Cl-2, Ru(phen)(PPh3)(2)Cl-2. Ru(dppz-Cl)(PPh3)(2)Cl-2, Ru(phen)(CO)(2)Cl-2, Ru(bpy)(CO)(2)Cl-2 and Ru(dppz)(CO)(2)Cl-2 (where dppz: dipyrido[3,2-a:2',3'-c]phenazine, dppz-Cl: 10-chlororodypirido[3,2-a:2',3'-c] phenazine, phen: 1,10-phenanthroline and bipy: 2,2'-bipyridine) are reported. The ruthenium complexes show high activity as catalysts in the hydrogenation reaction of N-benzylideneaniline and the hydrogen transfer reaction. The products of the catalysis were obtained with conversions between 21 and 91% after 2 h of reaction. The Ru(phen)(CO)(2)Cl-2 complex was the catalyst that showed the highest conversion (91%) for the hydrogenation of N-benzylideneaniline. The complexes Ru(dppz)(PPh3)(2)Cl-2, Ru(bpy)(PPh3)(2)Cl-2 and Ru(dppz)(CO)(2)Cl-2 showed 99% conversion in the hydrogen transfer reaction.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceInorganic Chemistry Communications
dc.subjectHomogeneous catalysis
dc.subjectImine hydrogenation
dc.subjectRuthenium hydrogenation
dc.titleRuthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of N-benzylideneaniline hydrogenation
dc.typeArtículo de revista


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